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PATRIOTIC POUR

INTRODUCTION

This activity uses color and surprise to illustrate the principle of density.  Because of its colorful nature, it is a nice activity to use with young children.  However, the principle demonstrated also makes it a worthwhile activity for upper elementary age children.  We use this experiment for  "Color-full", "Density", and "Environmental" topics.
 

PURPOSE

Used with younger children, the color and the surprise of this activity help to get them excited about the subject of Science.  For children in the upper elementary grades, it is an excellent demonstration of the principle that different liquids have different densities and also shows that oil and water are immiscible. 
 

MATERIALS

Milk 
Blue Lamp Oil (see NOTE below)
Colorless Corn Syrup dyed red with food coloring (see NOTE below)
Jar about 1 1/2" in diameter, with no "shoulders"; with screw-on lid
Paper sleeve for the jar that can be slipped on or off easily
 

PREPARATION FOR THE ACTIVITY

We keep a packet of nonfat dry milk powder in the activity packet and make up about one-eighth cup (2 tablespoons) of milk just prior to class.  Regular milk works better if you don't have to worry about spoilage. 

To color the corn syrup, heat the corn syrup (lid off) in your microwave oven for about one minute, or until it becomes more fluid.  Add 10-15 drops of red food coloring to the corn syrup, cap the bottle, and shake until the food coloring is evenly dispersed throughout the syrup.  You may need to add more food coloring to get a deep red color.

NOTE:  If you are unable to find blue lamp oil, but red lamp oil is available, you can dye the corn syrup blue. 
 

PROCEDURE

With young children, ask what colors are used to make green, orange, and purple.  Second graders usually know these combinations, and older first graders do, too.  Then ask them what happens if you add the color white to purple.  Many of the children will know that this will make the purple a lighter purple color. 

Show them your three liquids: red corn syrup, white milk, and blue lamp oil.  Tell them that you are going to pour the three liquids into your jar (which should be hidden inside the paper sleeve).  Pour at least a 1/2" layer of each liquid into the jar, being careful to use more oil than milk (see NOTE below).  Cap the jar and ask the children what color they will see in the jar.  ("Light purple!")  Pull the sleeve off the jar, and you will find the liquids have layered and remain red, white, and blue. 

For children in second grade and up, it is even more surprising if you pour the lamp oil in first, as they expect it to go to the bottom of the jar and stay there. 

Ask the children what will happen if you turn the jar upside down or place it on its side.  Discuss the results.  At this point, they may notice that the white milk and red corn syrup are beginning to mix.  Discuss why these two liquids are mixing, noting that the blue remains separate.

Finally, the children always want you to shake the jar.  Be sure the top is screwed on tightly and then shake the jar hard enough to mix the liquids together.  Hold the jar up and observe what happens.  Discuss the results.
 

EXPLANATION

The density of a substance is determined by dividing its mass by its volume.  The liquids stay in layers due to the differences in density.  The corn syrup, a solution of water and a great deal of sugar, is the most dense (weighs the most for the same volume of liquid) and thus goes to the bottom of the jar.  The lamp oil is the least dense, and goes to the top, while the milk layer is in between.  Even when poured into the jar first, the lamp oil will go to the top as the more dense syrup and milk go through and settle underneath the oil layer.
When you change the position of the jar to upside down and/or on its side, you have done nothing to change the properties of the liquids, and so the least dense (oil) will still go back to the top of the more dense liquids. 
The corn syrup and milk begin to mix because they are both water mixtures, while the oil does not like to mix with water, and so stays separate. 
When you shake the liquids together, the liquids do combine, but the lamp oil layer comes back out on top very quickly, to the children's delight.  NOTE:  Some of the milk and oil will form an emulsion so the oil will be unable to separate.  To avoid this problem, use more oil than milk (about 1 1/2 times as much) so that not all of the oil will be emulsified and an oil layer will still separate from the water/corn syrup layer. 
 

ADDITIONAL SUGGESTIONS

For older children, this experiment easily leads into an environmental discussion regarding oil spills and the importance of the fact that the oil layer forms on top of the water.  If the oil sank to the bottom of the ocean, lake, etc., much more harm would be done and clean-up of the oil would be very difficult.

If there is a greater volume of lamp oil than corn syrup in the jar, young children may have a difficult time understanding that the oil is still "lighter" than the syrup.  They also often surmise that the milk must be the "heaviest" liquid because it is strong enough to hold the other two liquids apart.  To help them understand that both volume and mass need to be considered, use 2 common objects with very different volumes, such as a partially inflated balloon and a baseball, or a book and a larger piece of foam.  Use a simple balance to determine the mass of each object, so they can see that even though one object is larger than another, the larger object may still be lighter (and thus less dense) than the smaller one.  (Which weighs more - a pound of feathers or a pound of lead?)  You can also pour a little more corn syrup into the jar (before you shake the jar to mix the liquids) and let the children watch as the heavy syrup goes straight through the oil and milk layers and settles at the bottom. You could illustrate this concept another way, by dropping a rock in a bucket of water.  It will sink to the bottom immediately, while a chunk of wood of approximately the same size would quickly bounce back to the top of the water because it is much lighter, i.e. less dense.
 

DISPOSAL

Pour as much of the lamp oil as possible back into your bottle of lamp oil.  If a little of the milk/syrup mixture goes into the bottle, it will sink to the bottom,, remain there, and not cause any problems when a new oil sample is poured from the bottle.  You may need to use a medicine dropper or a plastic pipette to remove most of the remaining oil, adding it to the bottle of oil.  Dispose of the remaining very small amount of oil along with the syrup/milk solution by flushing it down a sink drain. 
 

REFERENCES

Andy Sae, "Red, White, and Blue", Chemical Magic from the Grocery Store, Eastern New Mexico State University, Clovis, NM, 1991, pp. 8-9.
 
 
 
Kids Involved Doing Science is at http://www.kids.union.edu          Modified 02/23/2001  by C. & P. Scaife